Twelve-connected porous metal-organic frameworks with high H(2) adsorption.
نویسندگان
چکیده
The twelve-connected metal-organic frameworks {[Ni(3)(OH)(L)(3)].n(solv)}(infinity) and {[Fe(3)(O)(L)(3)].n(solv)}(infinity) [LH(2) = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H(2) up to 4.15 wt% at 77 K.
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ورودعنوان ژورنال:
- Chemical communications
دوره 8 شماره
صفحات -
تاریخ انتشار 2007